Comparison of Main Arsenic Removal Technologies
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Technology
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Advantage
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Disadvantage
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Oxidation and sedimentation: air oxidation, chemical oxidation
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Relatively simple, low cost, but slow process (air)
Relatively simple and rapid process (chemical)
Oxidizes other impurities and kills microbes
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Processes remove only some of the arsenic
Used as pretreatment for other processes
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Coagulation and filtration: alum coagulation, iron coagulation
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Relatively low capital cost
Relatively simple in operation
Common chemicals available
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Not ideal for anion-rich water treatment (e.g. containing phosphates)
Produces toxic sludge
Low removal of As(III)
Preoxidation is required
Efficiencies may be inadequate to meet strict standards
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Sorption techniques: activated alumina, iron-coated sand, ion exchange resin, other sorbents
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Relatively well known and commercially available
Well-defined technique
Many possibilities and scope for development
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Not ideal for anion-rich water treatment (e.g. containing phosphates)
Produces arsenic-rich liquid and solid wastes
Replacement/regeneration is required
High-tech operation and maintenance
Relatively high cost
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Membrane techniques: nanofiltration, reverse osmosis
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Well-defined and high removal efficiency
No toxic solid wastes produced
Capable of removal of other contaminants
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High capital and running costs
High-tech operation and maintenance
Arsenic-rich rejected water is produced
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Source: World Bank Technical Report, Volumn II: Arsenic Contamination of ground water in South and East Asian countries
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In-situ treatment Vs Filtration Techniques
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In-situ Technique
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Point of Difference
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Filter techniques
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After treating water for 45 days, As & Fe content went well below WHO guidelines. Fe content in the water is a boon to this technique.
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Efficiency
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The filters get clogged up with iron and needs frequent recharging/re-activation. Often these filter beds are expensive.
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With minimum maintenance, it can run for 10 years. But within that time, huge amount of arsenic will be trapped within the soil particles. Periodic oxidation will keep them trapped for decades.
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Longivity
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They require frequent sludge removal & recharge every 4-5 month.
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1 to 2 months after starting of the plant.
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Start-up time
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Instant startup.
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$ 5 per month for 3000lt/day plant
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Maintenance Cost
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100$ for 4 months limited use.
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Village plumbers & electricians can maintain it.
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Expertise to maintain
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Specially trained technicians & particular chemicals are required for maintenance.
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Any person with basic training.
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Operation
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A caretaker may be needed.
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Highly sustainable process. Source treatment.
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Sustainability
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No sustainability issue. Point Treatment.
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The aquifer is being restored to its previous arsenic free condition.
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Natural resource restoration
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Only the pumped up ground water is treated.
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Minimum iron-arsenic precipitate generation for 3 months. After that, waste generation is nil.
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Waste generation
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A cosiderable quantity of iron & arsenic sludge is produced every day. The waste management becomes a problem.
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